Looks like a female from the body shape - she's got "curvy hips".
Peat moss will soften water, but it all depends on where you start from. It's a bit like putting salt on a snowy driveway. If there's three feet of snow, you'll need an awful lot of salt, where if there is three inches, you'd get away with half a shovelful or so. Similarly, if you start out with water that is 300+ ppm TDS (and mainly calciumbicarbonat - so typically hard water), then you'd need a big bag of peat to make a small amount of soft water... So whilst it can be done, it's not very practical. If you have medium hard water or soft, you may be able to get away with using peat.
I had a look at this:
http://www.qualitywatertreatment.com/ci ... _guide.htm
and looked up Greensboro - but it's looking like you are close to the "harder water" parts of NC [if I'm looking at the right place - it's not an area of the US that I've spent much time in - I've been to Charleston, SC and up in New York, but that's a long way from Greensboro...]
Rainwater should be soft, and as per discussions elsewhere, unless you live in a heavily polluted area, should be OK to use in your aquarium. Only slight problem is variable levels of supply - so you either need large storage or an alternative when it doesn't rain for a few weeks. [And of course, a suitable way of collecting the rainwater - I live in a flat, and I don't have any way that I could store collect rainwater without interfering with my downstairs neighbour...]
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Mats